PUBLICATIONS

      


  • Coordination Compounds of Nickel Palladium and Platinum, A. Zarkadoulas, C.A. Mitsopoulou, Photochemistry and Photophysics of Coordination Compounds. Fundamentals and Applications 1st edition Ed. Rameta, A. Rai, J. Bhat, S Bhardaj, A. Ameta Elsevier, 2023 Chapter 9, 255 -292

  • Reconciling Local Coupled Cluster with Multireference Approaches for Transition Metal Spin-State Energetics, M. Drosou; C. A. Mitsopoulou; D. A. Pantazis,., Journal of Chemical Theory and Computation, 2022, 18, 3538–3548.

  • EPR Spectroscopy of Cu(II) Complexes: Prediction of g-Tensors Using Double-Hybrid Density Functional Theory, M. Drosou, C. A. Mitsopoulou, M. Orio and D. A. Pantazis, Magnetochemistry, 2022, 8(4), 36; https://doi.org/10.3390/magnetochemistry8040036 ((This article belongs to the Special Issue EPR Spectroscopy in Chemistry and Biology)

  • Structural modifications on nickel dithiolene complexes lead to increased metal participation in the electrocatalytic hydrogen evolution mechanism, M. Drosou, A. Zarkadoulas, K. Bethanis and, JC. A. Mitsopoulou, J. Coord. Chem., 2021, 74(9,10) 1424-1442.

  • Spin-state energetics of manganese spin crossover complexes: Comparison of single-reference and multi-reference ab initio approaches, M. Drosou, C. A. Mitsopoulou, D. A. Pantazis, Polyhedron, 2021 (208) 115399. https://doi.org/10.1016/j.poly.2021.115399

  • Antifungal and antiaflatoxigenic assessment of new Cu(II)–pq complexes against Aspergillus parasiticus, in dark conditions and under visible irradiation’ E. Lioli, E. Kollia, P. Markaki, C. A Mitsopoulou, FEMS Microbiology Letters, 2021, 368 (19), https://doi.org/10.1093/femsle/fnab136

  • Synthesis, DNA-Binding, Anticancer Evaluation, and Molecular Docking Studies of Bishomoleptic and Trisheteroleptic Ru-Diimine Complexes Bearing 2-(2-Pyridyl)-quinoxaline S. Balou, A. Zarkadoulas, M. Koukouvitaki, L. Marchio, E.K. Efthimiadou, and C. A. Mitsopoulou, Bioinorganic Chemistry and Applications, 2021, Article ID 5599773, 16 pages https://doi.org/10.1155/2021/5599773

  • Heteroleptic thiolate diamine nickel complexes: Noble-free-metal catalysts in electrocatalytic and light-driven hydrogen evolution reaction, F. Kamatsos, M. Drosou, C.A.Mitsopoulou, International Journal of Hydrogen Energy 2021, 26 (37), 19705-19716. https://doi.org/10.1016/j.ijhydene.2021.02.005

  • Synthesis of Novel Heteroleptic Oxothiolate Ni(II) Complexes and Evaluation of Their Catalytic Activity for Hydrogen Evolution, F. Kamatsos, K. Bethanis and C. A. Mitsopoulou, Catalysts 2021, 11, 401-419. 10.3390/catal11030401

  • Synthesis, characterization of ((CH3) 3S) 2SnI6-nCln and ((CH3) 3S) 2SnI6-nBrn (n= 1, 2) perovskites and use in dye-sensitized solar cells, M. M. Elsenety, M. Antoniadou, A. Kaltzoglou, A. G Kontos, A. I Philippopoulos, C. A Mitsopoulou, P. Falaras, Materials Chemistry and Physics, 2020, 239, 122310

  • Recent advances on the mechanisms of hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes, M. Drosou, F. Kamatsos, C.A Mitsopoulou, Inorg. Chem. Front., 2020, 7, 37-71. DOI: 10.1039/C9QI01113G

  • Surfactant Effects on the Synthesis of Redox Bifunctional V2O5 Photocatalysts, I.Ibrahim, G.V. Belessiotis, M.K. Arfanis, C Athanasekou, A.I. Philippopoulos, C.A Mitsopoulou, G.E.  Romanos, P. Falaras, Materials, 2020, 13, 4665. doi:10.3390/ma13204665

  • Reactivity and Mechanism of Photo- and Electrocatalytic Hydrogen Evolution by a Diimine Copper(I) Complex’ M. Drosou, F. Kamatsos, G. Ioannidis, A. Zarkadoulas, C. A. Mitsopoulou, C. Papatriantafyllopoulou and D. Tzeli, Catalysts, 2020, 10, 1302; doi:10.3390/catal10111302

  • Synthesis, characterization, DNA binding and cytotoxicity studies of two novel Cu(II)-2-(2′-pyridyl) quinoxaline complexes, E. Lioli,V. Psycharis, E. K.Efthimiadou, C. A.Mitsopoulou, Journal of Inorganic Biochemistry, 2020,  208, 111077, https://doi.org/10.1016/j.jinorgbio.2020.111077

  • Establishing Structure – Activity Relationships in Photocatalytic Systems using Nickel bis–Dithiolene Complexes as Proton Reduction Catalysts" by Eugenia Koutsouri; Athanasios Zarkadoulas; Christina Kefalidi; Constantina Papatriantafyllopoulou; Christiana Mitsopoulou,European Jornal of Inorganic Chemistry (EJIC), 2019 Volume2019, Issue46December 15, 2019 Pages 4908-4919 http://dx.doi.org/10.1002/ejic.201900886

  • Photocatalytic hydrogen production with alkylated nickel bis–dithiolene complexes, Athanasios Zarkadoulas, Eugenia Koutsouri, Emmanouil Semidalas, Vassilis Psycharis, Catherine P. Raptopoulou, Christiana A. Mitsopoulou, Polyhedron (2018), https://doi.org/10.1016/j.poly.2018.06.029, 152 (2018)138-146.

  • Proton reduction reaction catalyzed by homoleptic nickel bis-1,2-dithiolate complexes: Experimental and theoretical mechanistic investigations., A. Zarkadoulas, M. J. Field, V. Artero, C. A. Mitsopoulou, ChemCatChem, (2017), 9. 2308-2317 DOI:10.1002/CCTC.201601399

  • Synthesis, characterization and crystal structure of rhenium(I) tricarbonyl diimine complexes coupled with their efficiency in producing hydrogen in a photocatalytic system, Kefalidi, C., Koutsouri, E., Marchiò, L., A. Zarkadoulas, Efstathiadou, S., Mitsopoulou, C.A., Polyhedron (2016),110, pp. 157-164

  • Photocatalytic Hydrogen Evolution by tris-dithiolene tungsten complexes’’, E. Koutsouri, C.A. Mitsopoulou, Open Chem., (2016); 14:1-11

  • Rhenium complexes in homogeneous hydrogen evolution, A. Zarkadoulas, E. Koutsouri, C. Kefalidi, C.A. Mitsopoulou, Coordination Chemistry Reviews (2015), 304, 55-72

  • Experimental and Theoretical Insight into Electrocatalytic Hydrogen Evolution with Nickel Bis(aryldithiolene) Complexes as Catalysts , A. Zarkadoulas · M. J. Field · C. Papatrianta-fyllopoulou, V. Artero, · C. A. Mitsopoulou,  Inorg. Chem.(2015) 55 (2), 432-444

  • Role of the acceptor in tuning the Properties of Metal [M(II)=Ni, Pd, Pt] Dithiolato/Dithione (Donor/Acceptor) Second-Order Nonlinear Chromophorew:Combined Experimental and theoretical Studies” Davide Espa, Luca Pilia, Christodoulos Makedonas, Luciano Marchiò, Maria Laura Mercuri, Angela Serpe Alberto Barsella, Alain Fort, Christiana A. Mitsopoulou*, and Paola Deplano*,Inorg. Chem., 2014, dx.doi.org/10.1021/ic402738b I Inorg.Chem. Inorg. Chem., 2014, 53 (2), pp 1170–1183

  • Re(I) tricarbonyl complex of 1,10-phenanthroline-5,6-dione: DNA binding, cytotoxicity, anti-inflammatory and anti-coagulant effects towards Platelet Activating Factor, Michael Kaplanis, George Stamatakisb, Vasiliki D. Papakonstantinoub, Maria Paravatou-Petsotasc, Constantinos A. Demopoulosb, C. A. Mitsopoulou, http://dx.doi.org/10.1016/j.jinorgbio.2014.02.003, J. Biol. Inorg. Chem. (2014), 135, 1-9

  • Combining photosensitizers: The case of [Cl2Pt(bpym)Re(CO)3Cl] and its dithiolate analogs’ Polyhedron, Eugenia Koutsouri, Athanasios Zarkadoulas, Christodoulos Makedonas, Charalampos Koumbounis, Patrina Paraskevopoulou, Christiana A. Mitsopoulou, Polyhedron Volume 52, (2013), Pages 234-245 Alfred Werner Special Issue 2013 (by invitation).

  • ‘A perspective on solar energy conversion and water photosplitting by dithiolene complexes’ A. Zarkadoulas, E. Koutsouri, C.A. Mitsopoulou,  Coord. Chem. Rev. (2012), 256, 2424-2434. Coord. Chem. Rev. 256 “Solar Fuels”, 2424 (by invitation).

  • Combined Experimental and Theoretical Study on Redox-Active d8 Metal Dithione-Dithiolato Complexes Showing Molecular Second-order Non-linear Optical Activity L. Pilia, D. Espa, A. Barsella,b A. Fort, C. Makedonas, L. Marchiò, M.L. Mercuri, Angela Serpe, C.A. Mitsopoulou,* P. Deplano. Inorg. Chem., 2011, 50 (20), 10015-10027

  • Identifying of charge- transfer transitions and reactive centers in M(diimine)(dithiolate) Complexes by DFT techniques,. C.A. Mitsopoulou, Coord. Chem. Rev., 2010, 254 (13), 1448-1456.

  • Isolation, Characterization and Computational Studies of the Novel (M3(μ3-Br)2(μ|-Br)3Br6]2- Cluster Anion", Paraskevopoulou, P.; Makedonas, C.;Psaroudakis, N.; Mitsopoulou, C.A.; Floros, G.;Seressioti, A.; Ioannou, M.; Sanakis, Y.; Rath, N.; Gomez-Garcia, C.; Stavropoulos, P.; Mertis, K,  Inorg. Chem. 2010, 49 (5), 2068-2076.

  • Synthesis, Characterization,,DNA binding, and Photocleavage Activity of Oxorhenium(V) Complexes with alpha Diimine and Quinoxaline Ligands, C. A. Mitsopoulou, A. Dagas, Bioinorg. Chem. & Appl,. (2010), Artcl. Num.: 973742   DOI: 10.1155/2010/973742   

  • Characterization and DNA interaction of the Pt(II) (pq)(bdt) complex. A theoretical and experimental research." has been accepted for publication in Inorganica Chimica Acta, C.A. Mitsopoulou*, C. Dagas, C. Makedonas, Inorg. Chim. Acta, 361 (2008) 1973-1982.

  • Synthesis, structural and DFT studies of a peroxo-niobate complex of the biological ligand 2-quinaldic acid’ A. Maniatiakou, C. Makedonas, C.A. Mitsopoulou, C. Raptopoulou, I. Rizopoulou, A. Terzis, A. Karaliota, Polyhedron 27 (2008) 3398-3408.

  • Synthesis, spectroscopic properties and crystal structure of mononuclear tricarbonylrhenium(I) chloride complexes carrying 6-functionalised quinoxalines” I. Veroni, C.A. Mitsopoulou, F.J.Lahoz, J. Organomet. Chem., 693 (2008), 2451-2457.

  • Synthesis, characterization, DFT studies and DNA binding of mixed platinum (II) complexes containing quinoxaline and 1,2-dithiolate ligands, Journal of Inorganic Biochemistry, C. A. Mitsopoulou, C. E. Dagas, C. Makedonas J. Ιnorg. Biochemistry, 102, (2008) 77-86.

  • Pentacarbonyl[2-(2 '-pyridyl)quinoxaline-kappa N-4]Tungsten: A Combined Study of its Conformational and Electronic Structure based on Experimental and DFT-TDDFT Data", C. Makedonas, I. Veroni, C.A. Mitsopoulou*, Eur. J. Inorg. Chem. (1), (2007) 120-131.

  • W(CO)(4)(diimine) structure revised -Correlating structure to pi* back-bonding, Eur. J. Inorg. Chem, C. Makedonas, C.A. Mitsopoulou*, (1), (2007) 110-119

  • Synthesis, Characterization and Sensitization Properties of two Novel Mono and bis carboxyl-dipyrido-phenazine Ruthenium(II) Charge Transfer Complexes", C.A. Mitsopoulou, I. Veroni, A.I. Phillipopoulos, P. Falaras, J. Photoch. Photob. A. Chem., 191 (2007) 6-12

  • An experimental and theoretical study on DNA binding of mixed platinum(II) complexes’. C.-A. Mitsopoulou and C. Makedonas, J. Biol. Inorg. Chem. (2007), 1

  • Interaction and photocleavage of DNA and oligonucleosides by oxorhenium (V) complexes with a-diimine and quinoxaline ligands’ C.A. Mitsopoulou K. Dagas J. Biol. Inorg. Chem. (2007),

  • Introduction of Modified Electronic Parameters - Searching for a Unified Ligand Properties Scale through the Electrophilicity Index Concept’ Eur. J. Inorg.Chem., C. Makedonas, C. A. Mitsopoulou (26) (2007) 4176-4189

  • Tuning the properties of M(diimine)(dithiolate) complexes – The role of the metal and solvent effect. A combined experimental, DFT and TDDFT study’ C. Makedonas and C.A. Mitsopoulou, Inorg. Chim.Acta, 360 (2007) 3997-4009.

  • An Experimental and DFT Computational Study of a Novel Zerovalent tetracarbonyl Tungsten Complex of 2-(2'-pyridyl)quinoxaline, I. Veroni , C. Makedonas, A. Rontoyianni, C.A. Mitsopoulou*, J. Organomet. Chem., 691 (3), (2006) 267-281

  • An Investigation of the Reactivity of [(diimine)(dithiolato)M] Complexes using the Fukui Functions Concept", C. Makedonas, C.A. Mitsopoulou, Eur. J. Inorg. Chem (3) (2006) 590-598.

  • A Vibrational and DFT Study of M(diimine)(dithiolate) Complexes and their Complexation Route", Spectrochim. Acta A, C. Makedonas, C.A. Mitsopoulou, 64 (4) (2006) 918-930.

  • The Relationship between Aromaticity and Charge-Transfer Transitions: A Combined Study of Square-planar Metal Complexes based on DFT, NMR and Nucleus-independent Chemical Shifts", C. Makedonas, C.A. Mitsopoulou, Eur J. Inorg. Chem. (12), (2006) 2460-2468.

  • Isolation, X-ray Structure and Properties of an Unusual Pentacarbonyl(2,2'-pyridyl-quinoxaline) Tungsten complex ", I. Veroni, C.A. Mitsopoulou, F.J.Lahoz, J. Organomet. Chem, 691 (26), (2006) 5955-5963.

  • Synthesis and characterization of a novel complex Mo (CO)4(2,2-pyridyl-quinoxaline). An insight based on experimental and theoretical data, E.Veroni, A, Rontoyiani and C.A. Mitsopoulou,. Dalton Trans, (2) (2003) 255-260.

  • Synthesis, Characterization, and Crystal Structure of the Pd(phen)(bdt) Complex. A DFT and TDDFT Study of its Ground Electronic and Excited States Compared to those of Analogous Complexes, C. Makedonas, C.A. Mitsopoulou, F.J. Lahoz, A.Balana, Inorg. Chem. 42 (26), (2003) 8853-8865.

  • Hydrogen from water: Photocatalytic splitting of water with visible light., Autrey T., Xantheas SS, Li LY, Linehan JC, Franz JA, Katakis D, Mitsopoulou C, Sofianos Z, Bitterwolf TE, Abstracts of papers of Am. Chem. Soc. 224: 141-FUEL Part 1 AUG 18,  2002.

  • An investigation οf the reaction of Cu (II) ions with tris(4-methoxy)-and tris-(4-dimethylamino)-2-diphenyl-dithiolato-S,S’) tungsten (VI) complexes, C.A.Mitsopoulou, E.Lyris, S.Veltsos, D.Katakis, Inorg. Reaction Mechan.,3 (2001) 99-106.

  • Synthesis and characterization of mixed diimine-dithiolate ligand complexes and theoretical investigation of the *-accepting role of the diimine ligand, C.Makedonas, C.A. Mitsopoulou, J. Inorg. Biochem. 86 (2001) 326.

  • Synthesis of mixed 2-(2’-pyridyl)quinoxaline-dithiolene ligand complexes of Re and Mo and their characterization” C.A. Mitsopoulou*, I.Veroni, C.Dagas  J .Inorg. Biochem. 86 (2001) 34120.

  • Separation of biologically active lipids from red wine, E.Fragopoulou, T.Nomikos, S.Antonopoulou, C.A.Mitsopoulou, C.A.Demopoulos. J. Agric. Food Chem., 48 (2000)  1234.

  • Metal complexes of the Schiff base ligand L=1,2-bis(2’-pyridylmethyleneimino)benzene with Ni2+, Fe2+,and Cu2+, and their reactions with bridged bidentate ligands. The crystal structure of the complex [NiL(H2O)2}Cl2, A. Garoufis, S. Kasselouri, C.A. Mitsopoulou, J.Sletten, C.Papadimitriou and N. Hadjiliadis, Polyhedron, 18 (1999) 39-47.

  • Solvation and catalyst-substrate superstructure of a tungsten tri(dithiolene) complex dissolved in water-acetone. A molecular dynamic model calculation., J. Samios, D. Katakis, D. Dellis,  E. Lyris, and C.A. Mitsopoulou, J. Chem. Soc., Faraday Trans., 94 (1998) 3169-3175.

  • On the mechanism of action of thiamin enzymes,crystal strusture of 2-(-hydroxyetheyl)thiamin pyrophosphate (HETPP). Complexes of HETPP with zinc (II) and cadmium (II)., G.Malandrinos, M.Louloudi, C.A. Mitsopoulou, I.S. Butler, R. Bau and N. Hadjiliadis, JBIC, 3 (1998) 437-448.)

  • Mixed ligand Ru(II) complexes with 2,2’-bipyridine and 2-(2’-pyridyl)quinoxaline., A. Garoufis, A.Koutsodimou, N.Katsaros, C.A. Mitsopoulou, and N. Hadjiliadis, Polyhedron, 18 (1998) 361-369.

  • Photochemishe Wasserspaltung bei Einstrahlung von Photonrn des sichtbaren Bereiches, C.A. Mitsopoulou and D. Katakis, in “Photochemie-Konzepte, Methoden, Experimente” ed. D. Whrle, Wiley-VCH, 1998, Chapter 8, p.p. 422-426.

  • Photophysical study of the decomposition of water using visible light and tungsten tris(dithiolenes) as photosensitizers-catalysts, R. Humphry-Baker, C.A. Mitsopoulou, D.Katakis, and E. Vrachnou, J. Photochem. Photobiol. A: Chem., 114 (1998) 137-144.

  • New Catalysts in the photooxidation of water., E. Lyris, D.Argyropoulos, C. Mitsopoulou, D. Katakis and E.Vrachnou, J. Photochem. Photobiol. A: Chem., 108 (1997) 51-54.

  • Molecular Dynamics of tricarbonyl (n6-arene)chromium Complexes in Solid State:  13C Solid-State NMR Studies and X-ray Crystal Structure of (n6-C6HMe5)Cr(CO)3., P.J.Barrie, C.A.Mitsopoulou, M. Motevalli and E.W.Randall, J.Chem.Soc. Dalton Trans, (1997) 353-358.

  • 3-D Delocalisation in tris-1,2-dithiolenes. D. Argyropoulos, E. Lyris, C.A. Mitsopoulou και D. Katakis, J.Chem. Soc. Dalton Trans, (1997) (4), 615-621.

 

  • NMR of Compounds Containing -NH2, -NO2 and NO groups., E.W.Randall, C.A. Mitsopoulou, in "Supplement F2: The Chemistry of Amino, Nitroso, Nitro and Related Compounds." Ed. S.Patai, John Wiley and Sons, New York, (1996), Chapter 7, pp 295-337.

  • Second-order Paramagnetic Re(III) Complexes: Solid State Structure, Assignement of the 13C Magnetic resonance Spectra in Solution, and Partial Orientation in High Magnetic Fields" C.A.Mitsopoulou, N.Mahieu,  M.Motevalli, E.W.Randall, J.Chem.Soc. Dalton Trans., (1996) 4563-4566. 

  • Stereochemical Non-Rigidity and Geometrical Isomerism in six coordinate Trigonal Prismatic Complexes. The case of asymmetric Molybdenum and Tungsten tris- dithiolenes,  D. Argyropoulos, C.A. Mitsopoulou and D. Katakis, Inorg. Chem., 35 (1996), 5549-5554

  • Molecular Dynamics of  Pentamethylbenzenechromium-tricarbonyl: a 13C Solid-State NMR study", P. Barrie, C. Mitsopoulou, E. Randall, J. Chem. Soc. Dalton Trans., (1995) 2125-2128.

  • Synthesis, Cyclic voltammetric and Electrospray  Mass Spectrometric studies of tris-substituted 1,2 dithiolene complexes of tungsten and molybdenum,  P.Falaras,  C.Mitsopoulou,   D. Argyropoulos, E. Lyris, E. Vrachnou, D.Katakis, N.Psaroudakis, Inorg. Chem., 34, (1995) 4536-4542.

  • Photocatalytic splitting of water: Increase of conversion and/ or energy storage efficiency., D. Katakis, C. Mitsopoulou, E. Vrachnou, J. Photoch. Photobiol. A: Chem., 81 (1994) 103-106.

  • Photocatalytic splitting of water, D. Katakis, C. Mitsopoulou, J. Konstantatos,  E. Vrachnou,  P. Falaras,  J. Photoch. Photobiol. A: Chem., 68 (1992) 375-388,.

  • Dithiolenes:  A cheap alternative to platinum for catalytic dihydrogen formation. The case of tris-[1-(4-methoxyphenyl)-2 phenyl-1,2 etylenodithiolenic-S,S']tungsten. C.Mitsopoulou, J.Konstantatos, D.Katakis, E.Vrachnou. Journal of Molecular Catalysis. 67 (1991) 137-146.

  • A Tungsten Dithiolene as Catalyst and Photocatalyst." E.Vrachnou, C.Mitsopoulou, D.Katakis and J.Konstantatos. Photoconversion Processes for Energy and Chemicals: Energy from Biomass. (D.O.Hall and G.Grassi Ed.) Elsevier Applied Science, Vol. 5, (1989) 1098-115.

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